Introduction to Coordination Chemistry

Author: Geoffrey A. Lawrance

Publisher: John Wiley & Sons

ISBN: 1118681401

Category: Science

Page: 304

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At the heart of coordination chemistry lies the coordinate bond, inits simplest sense arising from donation of a pair of electronsfrom a donor atom to an empty orbital on a central metalloid ormetal. Metals overwhelmingly exist as their cations, but these arerarely met ‘naked’ – they are clothed in an arrayof other atoms, molecules or ions that involve coordinate covalentbonds (hence the name coordination compounds). These metal ioncomplexes are ubiquitous in nature, and are central to an array ofnatural and synthetic reactions. Written in a highly readable, descriptive and accessible styleIntroduction to Coordination Chemistry describes propertiesof coordination compounds such as colour, magnetism and reactivityas well as the logic in their assembly and nomenclature. It isillustrated with many examples of the importance of coordinationchemistry in real life, and includes extensive references and abibliography. Introduction to Coordination Chemistry is a comprehensiveand insightful discussion of one of the primary fields of study inInorganic Chemistry for both undergraduate and non-specialistreaders.

Text Book of Coordination Chemistry

Author: R. K. Sharma

Publisher: Discovery Publishing House

ISBN: 9788183562232

Category: Complex compounds

Page: 324

View: 890

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This book Power Series has been written for the students of B.A./B.Sc., of all Indian universities. Each chapter of this book contains complete theory and a fairly large number of solved examples. Sufficient problems have also been selected from various universities examination paper and included in the end of each chapter. Contents: Power Series and Double Series, Uniform Convergence, Fourier Series and Riemann Integral.

Physical Inorganic Chemistry

A Coordination Chemistry Approach

Author: S. F. A. Kettle

Publisher: Springer

ISBN: 3662251914

Category: Science

Page: 490

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GEORGE CHRISTOU Indiana University, Bloomington I am no doubt representative of a large number of current inorganic chemists in having obtained my undergraduate and postgraduate degrees in the 1970s. It was during this period that I began my continuing love affair with this subject, and the fact that it happened while I was a student in an organic laboratory is beside the point. I was always enchanted by the more physical aspects of inorganic chemistry; while being captivated from an early stage by the synthetic side, and the measure of creation with a small c that it entails, I nevertheless found the application of various theoretical, spectroscopic and physicochemical techniques to inorganic compounds to be fascinating, stimulating, educational and downright exciting. The various bonding theories, for example, and their use to explain or interpret spectroscopic observations were more or less universally accepted as belonging within the realm of inorganic chemistry, and textbooks of the day had whole sections on bonding theories, magnetism, kinetics, electron-transfer mechanisms and so on. However, things changed, and subsequent inorganic chemistry teaching texts tended to emphasize the more synthetic and descriptive side of the field. There are a number of reasons for this, and they no doubt include the rise of diamagnetic organometallic chemistry as the dominant subdiscipline within inorganic chemistry and its relative narrowness vis-d-vis physical methods required for its prosecution.

Synthetic Coordination Chemistry

Principles and Practice

Author: Julian A. Davies

Publisher: World Scientific

ISBN: 9789810220846

Category: Science

Page: 452

View: 9010

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Although coordination chemistry naturally centers on the synthesis of coordination compounds, the synthesis of these materials is typically not an end in itself. Coordination compounds are utilized in all branches of chemistry; from theoretical modeling to industrial and consumer products. While a large amount of information is available on coordination chemistry in general and synthetic methods in particular, no comprehensive work has been presented on the preparation of coordination compounds with an emphasis on synthetic strategies rather than on detailed descriptions of specific syntheses. The goal of this book is to provide an approach to coordination chemistry that is based upon preparative strategies.The main aim of the authors is to present a systematic classification of synthetic reactions rather than an encyclopedic listing of experimental results. Hence, the coverage is more selective than exhaustive. Despite this, the book provides access to the original literature with ca. 2000 references. The edition is well-illustrated and contains almost 250 schemes, figures and illustrations of crystal structures of selected complexes.

The Coordination Chemistry of Metalloenzymes

The Role of Metals in Reactions Involving Water, Dioxygen and Related Species

Author: Organización del Tratado del Atlántico Norte. Advanced Study Institute,NATO. Advanced Study Institute

Publisher: Springer Science & Business Media

ISBN: 9789027715302

Category: Science

Page: 391

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Assembling a program in bioinorganic chemistry that is scientifi cally relevant, well defined, and self-consistent is not an easy task. In this attempt we decided to consider zinc enzymes, copper oxidases, cytochromes and cytochrome oxidase. The choice is in part due to the great attention that the current specialized literature devotes to these topics, which are now debated among chemists, biochemists, biophysicists, etc .. We believe that hydration reactions, hydrolytic and oxidative processes have much in common from the point of view of the reaction mechanisms, the comprehension of which represents a frontier of science. For these reasons these topics have been the subject of the NATO-ASI held at San Miniato, Pisa, Italy, from May 28 to June 8, 1982. We hope we can transfer here the main conclusions of what (we believe) was a very stimulating scientific meeting. We would like to thank the local saving bank, Cassa di Risparmio di San Miniato, for helping in many ways. The financial contribution from the European Research Office of the US Army, and from the Bruker Spectrospin s.r.l., Italy, is also acknowledged. The National Science Foundation of the United States has provided a travel grant to one of the participants from the U.S.A. We are grateful to the NATO Scientific Affairs Division which provided a grant to finance this Institute.

Essentials of Coordination Chemistry

A Simplified Approach with 3D Visuals

Author: Vasishta Bhatt

Publisher: Academic Press

ISBN: 012803937X

Category: Science

Page: 282

View: 8809

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Essentials of Coordination Chemistry: A Simplified Approach with 3D Visuals provides an accessible overview of this key, foundational topic in inorganic chemistry. Thoroughly illustrated within the book and supplemented by online 3D images and videos in full color, this valuable resource covers basic fundamentals before exploring more advanced topics of interest. The work begins with an introduction to the structure, properties, and syntheses of ligands with metal centers, before discussing the variety of isomerism exhibited by coordination compounds, such as structural, geometrical and optical isomerism. As thermodynamics and kinetics provide a gateway to synthesis and reactivity of coordination compounds, the book then describes the determination of stability constants and composition of complexes. Building upon those principles, the resource then explains a wide variety of nucleophilic substitution reactions exhibited by both octahedral and square planar complexes. Finally, the book discusses metal carbonyls and nitrosyls, special classes of compounds that can stabilize zero or even negative formal oxidation states of metal ions. Highlighting preparations, properties, and structures, the text explores the unique type of Metal-Ligand bonding which enable many interesting applications of these compounds. Thoughtfully organized for academic use, Essentials of Coordination Chemistry: A Simplified Approach with 3D Visuals encourages interactive learning. Advanced undergraduate and graduate students, as well as researchers requiring a full overview and visual understanding of coordination chemistry, will find this book invaluable. Includes valuable visual content through 3D images and videos in full color, available online Provides a valuable introduction to the study of organic and inorganic ligands with metal centers Discusses advanced topics including metal carbonyls and nitrosyls

Medicinal Applications of Coordination Chemistry

Author: Chris J. Jones,John Thornback

Publisher: Royal Society of Chemistry

ISBN: 0854045961

Category: Science

Page: 353

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Metals in pharmaceuticals have played an increasingly important role in medicine over the last century, particularly in cancer therapy and diagnostic imaging methods. Medicinal Applications of Coordination Chemistry focuses on the role that transition metals play in clinical applications. Medicinal Applications of Coordination Chemistry begins with a brief historical review and an introduction to the chemistry of d- and f- block metals. Subsequent sections discuss metallodrugs for a number of different applications, the design of new drugs and the relationship between structure and function. Key sections include diagnostic applications of metal compounds in anatomical and functional imaging, and therapeutic applications of metals compounds. This book is ideal for researchers in academia and industry and comes complete with examples of real life applications.

Facets of Coordination Chemistry

Author: B. V. Agarwala,K. N. Munshi

Publisher: World Scientific

ISBN: 9789810214388

Category: Science

Page: 253

View: 9109

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A concise account of coordination chemistry since its inception is given here together with some of the newer significant facets. This book covers a broad spectrum of various topics on Environment, Cyclic Voltammetry, Chromatography, Metal Complexes of biological interest, Alkoxides, NMR spectroscopy and others. These are useful to the scientific community engaged in the field of Inorganic Chemistry and Analytical Chemistry.

Coordination Chemistry Research Progress

Author: Kevin S. Verley,Todd W. Cartere

Publisher: Nova Publishers

ISBN: 9781604560473

Category: Science

Page: 340

View: 4683

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Coordination chemistry is the study of compounds formed between metal ions and other neutral or negatively charged molecules. Coordination chemistry includes areas of inorganic solid state chemistry, organometallic chemistry and bioinorganic chemistry, as well as applications to analytical chemistry, catalysis, industrial chemistry and materials science.

Rare Earth Coordination Chemistry

Fundamentals and Applications

Author: Chun-Hui Huang

Publisher: John Wiley & Sons

ISBN: 0470824867

Category: Science

Page: 592

View: 9748

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Edited by a highly regarded scientist and with contributions from sixteen international research groups, spanning Asia and North America, Rare Earth Coordination Chemistry: Fundamentals and Applications provides the first one-stop reference resource for important accomplishments in the area of rare earth. Consisting of two parts, Fundamentals and Applications, readers are armed with the systematic basic aspects of rare earth coordination chemistry and presented with the latest developments in the applications of rare earths. The systematic introduction of basic knowledge, application technology and the latest developments in the field, makes this ideal for readers across both introductory and specialist levels.

Alfred Werner

Founder of Coordination Chemistry

Author: George B. Kauffman

Publisher: Springer Science & Business Media

ISBN: 3662111047

Category: Science

Page: 128

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Modern Coordination Chemistry

The Legacy of Joseph Chatt

Author: Neil Winterton,Jeff Leigh

Publisher: Royal Society of Chemistry

ISBN: 1847551483

Category: Science

Page: 404

View: 8383

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Coordination chemistry, as we know it today, has been shaped by major figures from the past, one of whom was Joseph Chatt. Beginning with a description of Chatt's career presented by co-workers, contemporaries and students, this fascinating book then goes on to show how many of today's leading practitioners in the field, working in such diverse areas as phosphines, hydrogen complexes, transition metal complexes and nitrogen fixation, have been influenced by Chatt. The reader is then brought right up-to-date with the inclusion of some of the latest research on these topics, all of which serves to underline Chatt's continuing legacy. Intended as a permanent record of Chatt's life, work and influence, this book will be of interest to lecturers, graduate students, researchers and science historians.

Inorganic Chemistry

Author: A. F. Holleman,Egon Wiberg,Nils Wiberg

Publisher: Academic Press

ISBN: 9780123526519

Category: Science

Page: 1884

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Inorganic Chemistry easily surpasses its competitors in sheer volume and depth of information. Readers are presented with summaries that ease exam preparation, an extensive index, numerous references for further study, six invaluable appendixes, and over 150 tables that provide important data on elements at a quick glance. Now in its 101st printing, Inorganic Chemistry provides an authoritative and comprehensive reference for graduate students, as well as chemists and scientists in fields related to chemistry such as physics, biology, geology, pharmacy, and medicine. Translated for the first time into English, Holleman and Wiberg's book is a bestseller in Germany, where every chemist knows and values it. Prior to this translation, there was no equivalent to Holleman and Wiberg's book in English.

Applications of Graph Theory and Topology in Inorganic Cluster and Coordination Chemistry

Author: R. Bruce King

Publisher: CRC Press

ISBN: 9780849342981

Category: Science

Page: 240

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Applications of Graph Theory and Topology in Inorganic Cluster and Coordination Chemistry is a text-reference that provides inorganic chemists with a rudimentary knowledge of topology, graph theory, and related mathematical disciplines. The book emphasizes the application of these topics to metal clusters and coordination compounds. The book's initial chapters present background information in topology, graph theory, and group theory, explaining how these topics relate to the properties of atomic orbitals and are applied to coordination polyhedra. Subsequent chapters apply these ideas to the structure and chemical bonding in diverse types of inorganic compounds, including boron cages, metal clusters, solid state materials, metal oxide derivatives, superconductors, icosahedral phases, and carbon cages (fullerenes). The book's final chapter introduces the application of topology and graph theory for studying the dynamics of rearrangements in coordination and cluster polyhedra.

Quantum Chemistry: The Challenge of Transition Metals and Coordination Chemistry

Author: A. Veillard

Publisher: Springer Science & Business Media

ISBN: 9789027722379

Category: Science

Page: 530

View: 4685

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Over the last twenty years, developments of the ab initio metho dologies and of the computing capacities have progressively turned quantum chemistry into a predictive tool for molecular systems involving only light elements. The situation appears less advanced for systems containing transition metal elements where specific difficulties arise, like those 1inked to the quasi-degeneracy of the lowest atomic states. Correlation effects, which are important only for quantitative accuracy in the treatment of molecules made of light elements, need sometimes to be considered even for a qualitative des cription of transition metals systems (like the multiple metal-metal bond). The treatment of atoms of a high atomic number has necessited the development of model potential methods. These difficulties ex acerbate for systems containing several trans ition atoms a correct description of the dichromium molecule Crz still represents a challenge to quantum chemists. Yet many advances have been made recently in the theoretical treatment of these systems, despite the fact that our understanding still remains disparate with a variety of models and methodologies used more or less successfully (one-electron models, explicitly correlated ab initio methods, density functional formalisms). For these reasons, a NATO Advanced Research Workshop was organized to review in detail the state-of-the-art techniques and at the same time the most common applications. These encompass many fields including the spectroscopy of diatomics and small aggregates, structure and reactivity problems in organometallic chemistry, the cluster surface analogy with its implications for heterogeneous catalysis and the description of extended structures.

Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B

Applications in Coordination, Organometallic, and Bioinorganic Chemistry

Author: Kazuo Nakamoto

Publisher: John Wiley & Sons

ISBN: 9780470405871

Category: Science

Page: 400

View: 3909

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The 6th edition of this classic comprises the most comprehensive guide to infrared and Raman spectra of inorganic, organometallic, bioinorganic, and coordination compounds. From fundamental theories of vibrational spectroscopy to applications in a variety of compound types, it is extensively updated. Part B details applications of Raman and IR spectroscopy to larger and complex systems. It covers interactions of cisplatin and other metallodrugs with DNA and cytochrome c oxidase and peroxidase. This is a great reference for chemists and medical professionals working with infrared or Raman spectroscopies and for graduate students.